Department of Food Science, University of Guelph, Guelph, CanadaN1G 2W1.
Food Funct. 2012 Mar;3(3):327-37. doi: 10.1039/c2fo10202a. Epub 2012 Mar 1.
Ethylcellulose has been recently shown to be an excellent organogelator for vegetable oils. The resulting gels maintain the fatty acid profile of the vegetable oil used, but posses a solid-like structure that can be useful for the replacement of saturated fats in food products. Texture profile analysis and the back extrusion technique were used to assess the mechanical properties of canola, soybean, and flaxseed oil oleogels consisting of 10% ethylcellulose and 90% vegetable oil. Oils with a higher degree of unsaturation were shown to produce harder gels. Oleogels containing ethylcellulose of three molecular weights and reduced polymer concentrations from 4-10% ethylcellulose were also tested using the back extrusion technique, resulting in an increase in gel strength as polymer concentration and molecular weight increased. Therefore, oleogel strength was shown to be dependant on polymer molecular weight, concentration, and the fatty acid composition of the vegetable oil. Scanning electron microscopy was also used to provide a greater understanding of the gel's microstructure. In addition, frankfurters were made using canola oil oleogels to assess the possibility for replacement of the more highly saturated animal fat in such a product. Cooked frankfurters made with oleogels showed no significant differences in chewiness or hardness compared to the control products made with beef fat. These results provide the first in-depth characterization of ethylcellulose oleogels, and could potentially aid in the design/manufacture of ethylcellulose oleogels with specific textural properties to replace saturated fat in a variety of food products.
乙基纤维素最近被证明是一种极好的植物油有机凝胶剂。所得凝胶保持了所用植物油的脂肪酸组成,但具有类似固体的结构,可用于替代食品中的饱和脂肪。使用质地剖面分析和反向挤出技术评估了由 10%乙基纤维素和 90%植物油组成的菜籽油、大豆油和亚麻籽油油凝胶的机械性能。具有较高不饱和度的油显示出更硬的凝胶。使用反向挤出技术还测试了三种分子量的乙基纤维素和从 4-10%乙基纤维素降低的聚合物浓度的油凝胶,结果表明随着聚合物浓度和分子量的增加,凝胶强度增加。因此,油凝胶的强度取决于聚合物的分子量、浓度和植物油的脂肪酸组成。扫描电子显微镜也用于更深入地了解凝胶的微观结构。此外,还使用菜籽油油凝胶制作法兰克福香肠,以评估在这种产品中替代更高度饱和动物脂肪的可能性。与使用牛脂制成的对照产品相比,用油凝胶制成的熟法兰克福香肠在咀嚼性或硬度方面没有明显差异。这些结果首次对乙基纤维素油凝胶进行了深入表征,并可能有助于设计/制造具有特定质地特性的乙基纤维素油凝胶,以替代各种食品中的饱和脂肪。