Centre Universitaire Régional d'Interface, Université Sidi Mohamed Ben Abdallah, BP 2626, route d'Imouzzar-Fès, Morocco.
Talanta. 2012 Apr 15;92:15-25. doi: 10.1016/j.talanta.2011.11.077. Epub 2011 Dec 24.
The aim of this paper is to apply a new technique for the validation of quantitative analytical procedures based on Bayesian simulation and accuracy profile. Also, an original strategy for estimating measurement uncertainty by the same approach has been developed. The performance of our proposal was confirmed by application to analytical and bio-analytical methods. Compared to the classical strategy, the new approach has a more holistic character. It means that it is no longer necessary to know the various individual steps into which the analytical method can be broken down since this latter is taken as a whole. Furthermore, the Bayesian accuracy profile procedure allows to control the risk associated with the future use of the analytical method.
本文旨在应用一种新的技术，基于贝叶斯模拟和准确度轮廓来验证定量分析程序。同时，还开发了一种通过相同方法估计测量不确定度的原始策略。通过应用于分析和生物分析方法，验证了我们建议的性能。与经典策略相比，新方法具有更全面的特点。这意味着不再需要了解可以将分析方法分解成的各个单独步骤，因为该方法被视为一个整体。此外，贝叶斯准确度轮廓程序允许控制与未来使用分析方法相关的风险。
