在镍催化剂存在下，2H-氮丙啶发生意外的比例失调反应，生成（1E,3Z）-2-氮杂-1,3-二烯和芳族腈。
An unexpected disproportional reaction of 2H-azirines giving (1E,3Z)-2-aza-1,3-dienes and aromatic nitriles in the presence of nickel catalysts.
机构信息
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan.
出版信息
Chem Commun (Camb). 2012 Apr 11;48(29):3554-6. doi: 10.1039/c2cc30745f. Epub 2012 Mar 5.
PMID:22388440
Abstract
An unprecedented nickel-catalysed disproportional reaction of 2,3-diaryl-2H-azirines forming azabutadienes and aromatic nitriles was discovered. This reaction involves the cleavage of two bonds of the 2H-azirine framework, which provides a novel type of transformation of 2H-azirines.
摘要
研究发现了一种前所未有的镍催化的 2,3-二芳基-2H-氮丙啶的歧化反应，形成氮杂丁二烯和芳香腈。该反应涉及 2H-氮丙啶骨架的两个键的断裂，为 2H-氮丙啶的转化提供了一种新的类型。
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