手性氨基酸混合物的对映体富集。
Enantioenrichment in sublimed amino acid mixtures.
机构信息
Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense, 28040 Madrid, Spain.
出版信息
Chem Commun (Camb). 2012 Apr 14;48(30):3623-5. doi: 10.1039/c2cc18129k. Epub 2012 Mar 2.
PMID:22388769
Abstract
A real amplification of an initial enantiomeric excess can be detected when two amino acids are sublimed at high temperature, even if one of the components is a racemic compound that does not convert into a conglomerate by sublimation.
摘要
当两种氨基酸在高温下升华时，即使其中一种成分是外消旋化合物，通过升华不会转化为内消旋混合物，也可以检测到初始对映过量的真正放大。
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