Medium range order of bulk metallic glasses determined by variable resolution fluctuation electron microscopy.

Variable resolution fluctuation electron microscopy (FEM) experiments are implemented with hollow-cone dark-field transmission electron microscopy. Medium range order lengths of zirconium and iron based bulk metallic glasses and amorphous silicon nitride are determined from the FEM results. It shows that maximum normalized intensity variances of FEM images occur when their nominal resolution approaches the correlation length Λ of the amorphous materials. Additionally, differences in the length and magnitude of medium range order are compared between metallic and covalent bond amorphous materials.