Interfacial layering of a room-temperature ionic liquid thin film on mica: a computational investigation.

The structure of a thin (4 nm) [bmim][Tf(2)N] film on mica was studied by molecular dynamics simulations using an empirical force field. Interfacial layering at T=300 K and at T=350 K is investigated by determining the number- and charge-density profiles of [bmim][Tf(2)N] as a function of distance from mica, and by computing the normal force F(z) opposing the penetration of the ionic liquid film by a spherical nanometric tip interacting with [bmim][Tf(2)N] atoms by a short-range potential. The results show that layering is important but localised within ~1 nm from the interface. The addition of a surface charge on mica, globally neutralised by an opposite charge on the [bmim][Tf(2)N] side, gives rise to low-amplitude charge oscillations extending through the entire film. However, outside a narrow interfacial region, the resistance of the [bmim][Tf(2)N] film to penetration by the mesoscopic tip is only marginally affected by the charge at the interface. The results obtained here for [bmim][Tf(2)N]/mica are similar to those obtained using the same method for the [bmim][Tf(2)N]/silica interface, and agree well with experimental force-distance profiles measured on the latter interface at ambient conditions.