Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstrasse 400, P.O. Box 510119, 01314 Dresden, Germany.
Dalton Trans. 2012 Jun 28;41(24):7190-2. doi: 10.1039/c2dt12406h. Epub 2012 Mar 8.
Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.
通过扩展 X 射线吸收精细结构（EXAFS）光谱学结合密度泛函理论（DFT）计算，确定了高氯酸中四价铈（Ce(IV)）的水合物种为单核的单氧桥联双核配合物，而不是单核配合物。
