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线性不可逆类卡诺热机最大功率输出时的效率。

Efficiency at maximum power output of linear irreversible Carnot-like heat engines.

作者信息

Wang Yang, Tu Z C

机构信息

Department of Physics, Beijing Normal University, Beijing 100875, China.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jan;85(1 Pt 1):011127. doi: 10.1103/PhysRevE.85.011127. Epub 2012 Jan 18.

Abstract

The efficiency at maximum power output of linear irreversible Carnot-like heat engines is investigated based on the assumption that the rate of irreversible entropy production of the working substance in each "isothermal" process is a quadratic form of the heat exchange rate between the working substance and the reservoir. It is found that the maximum power output corresponds to minimizing the irreversible entropy production in two isothermal processes of the Carnot-like cycle, and that the efficiency at maximum power output has the form η(mP)=η(C)/(2-γη(C)), where η(C) is the Carnot efficiency, while γ depends on the heat transfer coefficients between the working substance and two reservoirs. The value of η(mP) is bounded between η(-)≡η(C)/2 and η(+)≡η(C)/(2-η(C)). These results are consistent with those obtained by Chen and Yan [J. Chem. Phys. 90, 3740 (1989)] based on the endoreversible assumption, those obtained by Esposito et al. [Phys. Rev. Lett. 105, 150603 (2010)] based on the low-dissipation assumption, and those obtained by Schmiedl and Seifert [Europhys. Lett. 81, 20003 (2008)] for stochastic heat engines which in fact also satisfy the low-dissipation assumption. Additionally, we find that the endoreversible assumption happens to hold for Carnot-like heat engines operating at the maximum power output based on our fundamental assumption, and that the Carnot-like heat engines that we focused on do not strictly satisfy the low-dissipation assumption, which implies that the low-dissipation assumption or our fundamental assumption is a sufficient but non-necessary condition for the validity of η(mP)=η(C)/(2-γη(C)) as well as the existence of two bounds, η(-)≡η(C)/2 and η(+)≡η(C)/(2-η(C)).

摘要

基于工作物质在每个“等温”过程中的不可逆熵产生率是工作物质与热源之间热交换率的二次形式这一假设,研究了线性不可逆类卡诺热机最大功率输出时的效率。研究发现,最大功率输出对应于类卡诺循环的两个等温过程中不可逆熵产生的最小化,并且最大功率输出时的效率具有形式η(mP)=η(C)/(2 - γη(C)),其中η(C)是卡诺效率,而γ取决于工作物质与两个热源之间的传热系数。η(mP)的值介于η(-)≡η(C)/2和η(+)≡η(C)/(2 - η(C))之间。这些结果与陈和严[《化学物理杂志》90, 3740 (1989)]基于内可逆假设得到的结果、埃斯波西托等人[《物理评论快报》105, 150603 (2010)]基于低耗散假设得到的结果以及施密德尔和塞弗特[《欧洲物理快报》81, 20003 (2008)]针对实际上也满足低耗散假设的随机热机得到的结果一致。此外,我们发现基于我们的基本假设,内可逆假设恰好适用于以最大功率输出运行的类卡诺热机,并且我们所关注的类卡诺热机并不严格满足低耗散假设,这意味着低耗散假设或我们的基本假设是η(mP)=η(C)/(2 - γη(C))以及两个界限η(-)≡η(C)/2和η(+)≡η(C)/(2 - η(C))存在的充分但非必要条件。

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