Graduate School of EEWS (WCU), Department of Materials Science & Engineering, KAIST, Daejeon, Korea.
Phys Chem Chem Phys. 2012 Apr 21;14(15):5255-9. doi: 10.1039/c2cp40279c. Epub 2012 Mar 8.
Here, we find that doping sp(2) selective nitrogen, N sp(2), into carbon nanotube (CNT) channels induces a positive shift in the Fermi level of TiO(2) photoelectrodes. It is found that this results in the large diffusion coefficient of solar driven electrons for increasing the photocurrent as well as in the low recombination rate for improving open circuit voltage with 0.74 V, which could not be overcome by using pristine CNT channels with 0.66 V.
在这里,我们发现将 sp(2) 选择性氮,N sp(2),掺杂到碳纳米管 (CNT) 通道中会引起 TiO(2) 光电探测器费米能级的正移。结果发现,这导致了太阳能驱动电子的扩散系数增加,从而增加了光电流,同时复合率降低,开路电压提高到 0.74V,而使用原始 CNT 通道则无法克服这一问题,其开路电压为 0.66V。