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化学中的相对论效应:比你想象的更常见。

Relativistic effects in chemistry: more common than you thought.

作者信息

Pyykkö Pekka

机构信息

Department of Chemistry, University of Helsinki, Finland.

出版信息

Annu Rev Phys Chem. 2012;63:45-64. doi: 10.1146/annurev-physchem-032511-143755. Epub 2012 Jan 30.

Abstract

Relativistic effects can strongly influence the chemical and physical properties of heavy elements and their compounds. This influence has been noted in inorganic chemistry textbooks for a couple of decades. This review provides both traditional and new examples of these effects, including the special properties of gold, lead-acid and mercury batteries, the shapes of gold and thallium clusters, heavy-atom shifts in NMR, topological insulators, and certain specific heats.

摘要

相对论效应会强烈影响重元素及其化合物的化学和物理性质。几十年来,无机化学教科书已提及这种影响。本综述给出了这些效应的传统例子和新例子,包括金、铅酸电池和汞电池的特殊性质、金和铊簇的形状、核磁共振中的重原子位移、拓扑绝缘体以及某些比热。

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