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Chloridobis(1,2,3,4-tetra-hydro-1,4,6,11-tetra-aza-naphthacene-κN)copper(I).

作者信息

Chen Xing-Shun, Zhang Jing-Jing, Duan Tai-Ke, Chen Qun, Zhang Qian-Feng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m297. doi: 10.1107/S1600536812005582. Epub 2012 Feb 17.

DOI:10.1107/S1600536812005582
PMID:22412440
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3297250/
Abstract

In the title complex, [CuCl(C(14)H(12)N(4))(2)], the Cu(I) atom, lying on a twofold rotation axis, is coordinated by two N atoms of two 1,2,3,4-tetra-hydro-1,4,6,11-tetra-aza-naphthacene ligands and one Cl atom, also lying on the twofold rotation axis, in a distorted trigonal-planar geometry. The complex mol-ecules are connected into a one-dimensional structure along [001] via N-H⋯N hydrogen bonds and further into a three-dimensional structure via N-H⋯Cl hydrogen bonds. π-π inter-actions between the pyrazine and benzene rings and between the benzene rings [centroid-centroid distances = 3.5635 (15) and 3.9128 (16) Å] are present.

摘要

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本文引用的文献

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Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。
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