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N-(3-Chloro-benzo-yl)-2-nitro-benzene-sulfonamide.

作者信息

Suchetan P A, Foro Sabine, Gowda B Thimme, Prakash M Shet

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o786. doi: 10.1107/S160053681200640X. Epub 2012 Feb 17.

Abstract

In the title compound, C(13)H(9)ClN(2)O(5)S, the N-C bond in the C-SO(2)-NH-C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N-H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl ring is anti. The mol-ecule is twisted at the S-N bond, with a torsion angle of 65.41 (38)°. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 75.0 (1)°, and that between the sulfonyl and the benzoyl benzene ring is 89.1 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7378/3297855/46042744f232/e-68-0o786-fig1.jpg

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