Suchetan P A, Gowda B Thimme, Foro Sabine, Fuess Hartmut
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):o1773. doi: 10.1107/S1600536810023962.
In the title compound, C(13)H(9)Cl(2)NO(3)S·H(2)O, the conformation of the C=O bond is syn to the meta-Cl group in the benzoyl ring. The mol-ecules are twisted at the S-N bond with a C-S-N-C torsion angle of 72.9 (2)°. The dihedral angle between the sulfonyl benzene ring and the S-NH-C-O segment is 77.8 (1)° and that between the sulfonyl and benzoyl benzene rings is 80.5 (1)°. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (100) by N-H⋯O and O-H⋯O hydrogen bonds.
在标题化合物C(13)H(9)Cl(2)NO(3)S·H(2)O中，C=O键的构象与苯甲酰环中的间位氯原子基团呈顺式。分子在S-N键处发生扭曲，C-S-N-C扭转角为72.9 (2)°。磺酰基苯环与S-NH-C-O片段之间的二面角为77.8 (1)°，磺酰基苯环与苯甲酰基苯环之间的二面角为80.5 (1)°。在晶体中，分子通过N-H⋯O和O-H⋯O氢键连接成平行于(100)的二维网络。
