Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.
Chem Commun (Camb). 2012 May 11;48(37):4426-8. doi: 10.1039/c2cc30701d. Epub 2012 Mar 28.
A dynamic combinatorial approach for the synthesis of arylene ethynylene macrocycles (AEMs) from linear polymers is described. By using readily available carbazolyl-ethynylene copolymers as starting materials we obtained a number of novel macrocycles that would be difficult to prepare by traditional methods.
描述了一种从线性聚合物合成亚芳基乙炔大环(AEM)的动态组合方法。通过使用易得的咔唑基-乙炔共聚物作为起始材料,我们得到了一些通过传统方法难以制备的新型大环。