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通过超分子方法激活和放大前驱体簇的三阶 NLO 和发光响应。

Activation and amplification of the third-order NLO and luminescent responses of a precursor cluster by a supramolecular approach.

机构信息

College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu, PR China.

出版信息

Chem Commun (Camb). 2012 May 11;48(37):4480-2. doi: 10.1039/c2cc30581j. Epub 2012 Mar 29.

DOI:10.1039/c2cc30581j
PMID:22456423
Abstract

Solvothermal reactions of [Et(4)N][TpWS(3)(CuCl)(3)] (1) (Tp = hydridotris(3,5-dimethylpyrazol-1-yl)borate) with CuCN and KCu(CN)(2) afforded two [Tp*WS(3)Cu(3)]-based coordination polymers Tp*WS(3)Cu(3)(μ(3)-DMF){Cu(CN)(3)} (2) and KTp*WS(3)Cu(3)(μ(3)-DMF){Cu(2)(CN)(4.5)} (3). The third-order NLO and PL responses of 1 were activated and greatly amplified through its assembly via the Cu(CN)(3) and Cu(4)(CN)(9) species in 2 and 3.

摘要

[Et(4)N][TpWS(3)(CuCl)(3)]（1）（Tp= 氢代三(3,5-二甲基吡唑-1-基)硼酸盐）与 CuCN 和 KCu(CN)(2)的溶剂热反应得到了两个基于[Tp*WS(3)Cu(3)]的配位聚合物Tp*WS(3)Cu(3)(μ(3)-DMF){Cu(CN)(3)}（2）和 KTp*WS(3)Cu(3)(μ(3)-DMF){Cu(2)(CN)(4.5)}（3）。通过 2 和 3 中 Cu(CN)(3)和Cu(4)(CN)(9)物种的组装，1 的三阶 NLO 和 PL 响应被激活并大大放大。

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