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重新研究了分子氢的 v = 0 到 6 np 单线态里德伯系列的 J = 1 para 能级。

The J = 1 para levels of the v = 0 to 6 np singlet Rydberg series of molecular hydrogen revisited.

机构信息

Laboratoire de Physique Moléculaire pour l'Atmosphère et l'Astrophysique, UMR 7092 UPMC/CNRS, Université Pierre et Marie Curie, 4 place Jussieu 75252 Paris Cedex 05, France.

出版信息

J Chem Phys. 2012 Apr 7;136(13):134301. doi: 10.1063/1.3697967.

Abstract

The energies and the widths of the J = 1 para levels of the v = 0 to 6 Rydberg np singlet series of molecular hydrogen with absolute intensities of the R(0) and P(2) absorption lines were measured by a high - resolution synchrotron radiation experiment and calculated through a full ab initio multichannel quantum defect theory approach. On the basis of the agreement between theory and experiment, 31 levels were either reassigned or assigned for the first time.

摘要

通过高分辨率同步辐射实验测量了分子氢的 v = 0 到 6 Rydberg np 单线态系列的 J = 1 para 能级的能量和宽度,并通过全从头多通道量子亏损理论方法进行了计算。基于理论与实验的一致性,重新分配或首次分配了 31 个能级。

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