Laboratoire de Physique Moléculaire pour l'Atmosphère et l'Astrophysique, UMR 7092 UPMC/CNRS, Université Pierre et Marie Curie, 4 place Jussieu 75252 Paris Cedex 05, France.
J Chem Phys. 2012 Apr 7;136(13):134301. doi: 10.1063/1.3697967.
The energies and the widths of the J = 1 para levels of the v = 0 to 6 Rydberg np singlet series of molecular hydrogen with absolute intensities of the R(0) and P(2) absorption lines were measured by a high - resolution synchrotron radiation experiment and calculated through a full ab initio multichannel quantum defect theory approach. On the basis of the agreement between theory and experiment, 31 levels were either reassigned or assigned for the first time.
通过高分辨率同步辐射实验测量了分子氢的 v = 0 到 6 Rydberg np 单线态系列的 J = 1 para 能级的能量和宽度,并通过全从头多通道量子亏损理论方法进行了计算。基于理论与实验的一致性,重新分配或首次分配了 31 个能级。