一种灵活的连接卟啉二聚体的简便合成方法，该二聚体优先与富勒烯 C70 络合。
Facile synthesis of a flexible tethered porphyrin dimer that preferentially complexes fullerene C70.
机构信息
Hunter College and Graduate Center of the City University of New York, 695 Park Avenue, New York, New York 10065, USA.
出版信息
Chem Commun (Camb). 2012 May 16;48(39):4731-3. doi: 10.1039/c2cc31340e. Epub 2012 Apr 10.
Abstract
A simple, high yield, two-step synthesis yields a porphyrin dimer linked by a flexible dithiol tether that preferentially binds fullerene C(70) over C(60) in toluene solution. The complex forms stable aggregates when cast on glass.
摘要
一种简单、高产的两步合成方法得到了一个通过柔性二硫键连接的卟啉二聚体，该二聚体在甲苯溶液中优先与富勒烯 C(70)而不是 C(60)结合。当将该配合物浇铸在玻璃上时，会形成稳定的聚集体。
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本文引用的文献
1
Porphyrin Tessellation by Design: Metal-Mediated Self-Assembly of Large Arrays and Tapes.
Angew Chem Int Ed Engl. 1998 Sep 18;37(17):2344-2347. doi: 10.1002/(SICI)1521-3773(19980918)37:17<2344::AID-ANIE2344>3.0.CO;2-B.
2
Photoexcited state properties of H2-porphyrin/C60-based rotaxanes as studied by time-resolved electron paramagnetic resonance spectroscopy.
J Phys Chem A. 2011 May 26;115(20):5044-52. doi: 10.1021/jp202008j. Epub 2011 Apr 29.
3
Thin-film-based nanoarchitectures for soft matter: controlled assemblies into two-dimensional worlds.
Small. 2011 May 23;7(10):1288-308. doi: 10.1002/smll.201002350. Epub 2011 Apr 20.
4
Carbon nanotube wiring of donor-acceptor nanograins by self-assembly and efficient charge transport.
Angew Chem Int Ed Engl. 2011 May 9;50(20):4615-9. doi: 10.1002/anie.201007065. Epub 2011 Apr 14.
5
Fullerene-templated synthesis of a cyclic porphyrin trimer using olefin metathesis.
Chem Commun (Camb). 2011 Feb 7;47(5):1494-6. doi: 10.1039/c0cc04474a. Epub 2010 Dec 23.
6
Porphyrins as Molecular Electronic Components of Functional Devices.
Coord Chem Rev. 2010 Oct 1;254(19-20):2297-2310. doi: 10.1016/j.ccr.2010.05.014.
7
Recent progress in morphology control of supramolecular fullerene assemblies and its applications.
Chem Soc Rev. 2010 Nov;39(11):4021-35. doi: 10.1039/c000680g. Epub 2010 Sep 24.
8
Supramolecular donor-acceptor hybrids of porphyrins/phthalocyanines with fullerenes/carbon nanotubes: electron transfer, sensing, switching, and catalytic applications.
Chem Commun (Camb). 2009 Sep 7(33):4913-28. doi: 10.1039/b905753f. Epub 2009 Jul 3.
9
Single-molecule study on intermolecular interaction between C60 and porphyrin derivatives: toward understanding the strength of the multivalency.
Langmuir. 2009 Jun 16;25(12):6627-32. doi: 10.1021/la901360c.
10
Self-organized porphyrinic materials.
Chem Rev. 2009 May;109(5):1630-58. doi: 10.1021/cr8002483.
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