Jeon Hyeryeong, Lee Jaeyeon, Kim Myung Hwa, Yoon Juyoung
Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
Macromol Rapid Commun. 2012 Jun 14;33(11):972-6. doi: 10.1002/marc.201100882. Epub 2012 Apr 11.
Polydiacetylenes (PDAs), a family of conjugated polymers, are very intriguing materials in several aspects. Especially, the stimulus-induced apparent blue-to-red transition of the PDAs has led to the development of a variety of PDA-based chemosensors. In the current work, we synthesized PDA monomers bearing trimethyl amine (PCDA-DMEDA) and incorporated them with Poly(ethylene oxide) (PEO) into electrospun fibers. For the first time, we successfully demonstrated that PDA-based electrospun fibers can be used for the naked-eye detection of HCl gas by simple color change (blue to red).
聚二乙炔(PDA)是一类共轭聚合物,在多个方面都是非常有趣的材料。特别是,PDA受刺激诱导的明显蓝到红的转变已促使多种基于PDA的化学传感器得到发展。在当前工作中,我们合成了带有三甲胺的PDA单体(PCDA-DMEDA),并将它们与聚环氧乙烷(PEO)一起掺入电纺纤维中。首次成功证明基于PDA的电纺纤维可通过简单的颜色变化(蓝色到红色)用于肉眼检测HCl气体。