State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P R China.
Org Biomol Chem. 2012 May 14;10(18):3763-6. doi: 10.1039/c2ob25512j. Epub 2012 Apr 3.
An interesting gold(I)-catalyzed intramolecular hydroamination and ring-opening of sulfonamide-substituted 2-(arylmethylene)cyclopropylcarbinols has been described in this context. A variety of 4-substituted isoxazolidine derivatives were obtained in good to high yields through a highly regioselective cleavage of a carbon-carbon single bond in the cyclopropane.
在这种情况下，描述了一种有趣的金（I）催化的亚胺和磺酰胺取代的 2-（芳基亚甲基）环丙基甲醇的分子内环氨化和开环反应。通过在环丙烷中碳-碳单键的高度区域选择性断裂，得到了各种 4-取代的异恶唑烷衍生物，产率良好至高产率。
