通过 C-H 键活化生成 4-多氟芳基吡咯并[1,2-a]喹啉。
Generation of 4-polyfluoroaryl pyrrolo[1,2-a]quinolines via C-H bond activation.
机构信息
Department of Chemistry, Fudan University, Shanghai, China.
出版信息
Chem Commun (Camb). 2012 May 21;48(41):5028-30. doi: 10.1039/c2cc31301d. Epub 2012 Apr 12.
PMID:22497010
Abstract
A novel and efficient preparation of 4-polyfluoroaryl pyrrolo[1,2-a]quinolines via a palladium-catalyzed reaction of 1-[2-(2,2-dibromoethenyl)phenyl]-1H-pyrrole with polyfluoroarene is described. This transformation is efficient, leading to the corresponding products in good yields.
摘要
通过钯催化 1-[2-(2,2-二溴乙烯基)苯基]-1H-吡咯与多氟芳烃的反应，我们描述了一种新颖高效的制备 4-多氟芳基吡咯并[1,2-a]喹啉的方法。该转化具有高效性，能够以良好的收率得到相应的产物。
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