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基于有序 ZnO 纳米线阵列的固态染料敏化太阳能电池。

Solid-state dye-sensitized solar cells based on ordered ZnO nanowire arrays.

机构信息

Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA.

出版信息

Nanotechnology. 2012 May 25;23(20):205401. doi: 10.1088/0957-4484/23/20/205401. Epub 2012 Apr 30.

Abstract

A solid-state dye-sensitized solar cell (DSC) is fabricated by using arrays of 11-12 µm long, vertically oriented ZnO nanowires as the anode and CuSCN as the solid hole-transport material. The fabricated DSC yields a remarkably higher photocurrent density (J(SC) = 8 mA cm(-2)) compared to previously reported data for solid-state DSCs based on either one-dimensional nanostructures (J(SC) = 0.34 mA cm(-2)) or nanoporous nanocrystalline structures (J(SC) = 4.5 mA cm(-2)) of ZnO. A power conversion efficiency of 1.7% under an irradiation of AM 1.5 G simulated sunlight is reported.

摘要

采用阵列形式的 11-12 µm 长、垂直取向的 ZnO 纳米线作为阳极,并用 CuSCN 作为固态空穴传输材料,制备了固态染料敏化太阳能电池(DSC)。与之前报道的基于一维纳米结构(JSC = 0.34 mA cm-2)或 ZnO 纳米多孔纳米晶结构(JSC = 4.5 mA cm-2)的固态 DSC 的报道数据相比,所制备的 DSC 具有显著更高的光电流密度(JSC = 8 mA cm-2)。在 AM 1.5 G 模拟太阳光的照射下,报告的功率转换效率为 1.7%。

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