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连续体吸收 MT_CKD 模型的开发和最新评估。

Development and recent evaluation of the MT_CKD model of continuum absorption.

机构信息

Atmospheric and Environmental Research, Lexington, MA, USA.

出版信息

Philos Trans A Math Phys Eng Sci. 2012 Jun 13;370(1968):2520-56. doi: 10.1098/rsta.2011.0295.

Abstract

Water vapour continuum absorption is an important contributor to the Earth's radiative cooling and energy balance. Here, we describe the development and status of the MT_CKD (MlawerTobinCloughKneizysDavies) water vapour continuum absorption model. The perspective adopted in developing the MT_CKD model has been to constrain the model so that it is consistent with quality analyses of spectral atmospheric and laboratory measurements of the foreign and self continuum. For field measurements, only cases for which the characterization of the atmospheric state has been highly scrutinized have been used. Continuum coefficients in spectral regions that have not been subject to compelling analyses are determined by a mathematical formulation of the spectral shape associated with each water vapour monomer line. This formulation, which is based on continuum values in spectral regions in which the coefficients are well constrained by measurements, is applied consistently to all water vapour monomer lines from the microwave to the visible. The results are summed-up (separately for the foreign and self) to obtain continuum coefficients from 0 to 20 000 cm(-1). For each water vapour line, the MT_CKD line shape formulation consists of two components: exponentially decaying far wings of the line plus a contribution from a water vapour molecule undergoing a weak interaction with a second molecule. In the MT_CKD model, the first component is the primary agent for the continuum between water vapour bands, while the second component is responsible for the majority of the continuum within water vapour bands. The MT_CKD model should be regarded as a semi-empirical model with strong constraints provided by the known physics. Keeping the MT_CKD continuum consistent with current observational studies necessitates periodic updates to the water vapour continuum coefficients. In addition to providing details on the MT_CKD line shape formulation, we describe the most recent update to the model, MT_CKD_2.5, which is based on an analysis of satellite- and ground-based observations from 2385 to 2600 cm(-1) (approx. 4 μm).

摘要

水蒸气连续吸收是地球辐射冷却和能量平衡的一个重要贡献者。在这里,我们描述了 MT_CKD(MlawerTobinCloughKneizysDavies)水蒸气连续吸收模型的开发和现状。开发 MT_CKD 模型所采用的方法是约束模型,使其与大气光谱和实验室测量中外连续谱的质量分析相一致。对于现场测量,仅使用那些对大气状态的描述经过严格审查的情况。在未经过强制分析的光谱区域中的连续谱系数是通过与每个水蒸气单体线相关的光谱形状的数学公式来确定的。该公式基于在连续谱区域中的连续谱值,这些值是通过测量来很好地约束的,并且一致地应用于从微波到可见光的所有水蒸气单体线。结果被总结(分别针对外来和自),以获得从 0 到 20000cm-1 的连续谱系数。对于每个水蒸气线,MT_CKD 线形状公式由两个分量组成:线的指数衰减远翼加上水蒸气分子与第二个分子发生弱相互作用的贡献。在 MT_CKD 模型中,第一个分量是水蒸气带之间连续谱的主要因素,而第二个分量负责水蒸气带内的大部分连续谱。MT_CKD 模型应被视为具有已知物理强约束的半经验模型。使 MT_CKD 连续谱与当前观测研究保持一致,需要定期更新水蒸气连续谱系数。除了提供 MT_CKD 线形状公式的详细信息外,我们还描述了基于对 2385 至 2600cm-1(约 4μm)的卫星和地面观测的最新模型 MT_CKD_2.5 的更新。

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