Wuhan National Laboratory for Optoelectronics and College of Optoelectronic Science and Engineering, Huazhong University of Science and Technology, Wuhan, China.
Nanoscale. 2012 Jun 7;4(11):3350-8. doi: 10.1039/c2nr30440f. Epub 2012 May 1.
A multilayer TiO(2) nanorod-assembled cloth/nanorod array based electrode was fabricated by transferring different layers of TiO(2) nanorod-assembled cloth (TNRC) onto nanorod array grown on the conducting FTO substrate (titania nanorod, TNR). Combining the superior electron transport characteristics of TNR and outstanding optical properties of TNRC, the nanostructured electrode composed of two layers of TNRC meets the optimized design for high quality dye-sensitized solar cells (DSCs) and self-powered UV detectors. The highest efficiency of 4.02% for DSC under AM 1.5 was achieved with a high short circuit current density of 9.81 mA cm(-2), which was proved to be owing to the enhanced dye anchoring, light scattering and reduced charge recombination. For the photoelectrochemical (PEC) UV detector, the highest quantum efficiency of over 46% was obtained and a high photocurrent response of 0.271 mA cm(-2) was observed, together with the excellent self-powered, fast response and "visible blind" characteristics. A perfect linear response to the changed low-power signal indicates great potential for practical applications.
多层 TiO(2)纳米棒组装布/纳米棒阵列基电极是通过将不同层数的 TiO(2)纳米棒组装布(TNRC)转移到在导电 FTO 基底上生长的纳米棒阵列(TiO2 纳米棒,TNR)上而制备的。将 TNR 的优异电子传输特性和 TNRC 的出色光学性能相结合,由两层 TNRC 组成的纳米结构电极满足了高质量染料敏化太阳能电池(DSC)和自供电紫外探测器的优化设计。在 AM 1.5 下,DSC 的最高效率达到了 4.02%,短路电流密度高达 9.81 mA cm(-2),这归因于增强的染料固定、光散射和减少的电荷复合。对于光电化学(PEC)紫外探测器,获得了超过 46%的最高量子效率,并观察到 0.271 mA cm(-2)的高光电流响应,以及出色的自供电、快速响应和“可见盲”特性。对低功率信号变化的完美线性响应表明了其在实际应用中的巨大潜力。