Laboratoire de Chimie Organique et Spectroscopies Avancées (LCOSA), UMR 7515 au CNRS, Université de Strasbourg, Ecole de Chimie, Polymères, Matériaux de Strasbourg (ECPM), 25 rue Becquerel, 67087 Strasbourg Cedex 02, France.
J Org Chem. 2012 Jun 1;77(11):5036-48. doi: 10.1021/jo300477p. Epub 2012 May 14.
A methodological study is presented dealing with carbopalladation reactions on BODIPY dyes bearing aryl-halogen functions. Using this technique, several ester and amide groups were efficiently introduced on the dyes. These changes do not affect the optical properties of the dyes and thus allow the construction of new BODIPY-based functional dyes with carboxylic anchoring groups or peptide links.
本文介绍了一种涉及带有芳基卤官能团的 BODIPY 染料的碳钯化反应的方法研究。使用该技术，可以有效地在染料上引入几种酯基和酰胺基。这些变化不会影响染料的光学性质，因此可以构建具有羧酸锚固基团或肽键的新型基于 BODIPY 的功能染料。
