Department of Mechanical Engineering, Stanford University, Stanford, California 94305, United States.
Nano Lett. 2012 Jun 13;12(6):3121-6. doi: 10.1021/nl300996r. Epub 2012 May 14.
Thermal conduction in periodic multilayer composites can be strongly influenced by nonequilibrium electron-phonon scattering for periods shorter than the relevant free paths. Here we argue that two additional mechanisms-quasiballistic phonon transport normal to the metal film and inelastic electron-interface scattering-can also impact conduction in metal/dielectric multilayers with a period below 10 nm. Measurements use the 3ω method with six different bridge widths down to 50 nm to extract the in- and cross-plane effective conductivities of Mo/Si (2.8 nm/4.1 nm) multilayers, yielding 15.4 and 1.2 W/mK, respectively. The cross-plane thermal resistance is lower than can be predicted considering volume and interface scattering but is consistent with a new model built around a film-normal length scale for phonon-electron energy conversion in the metal. We introduce a criterion for the transition from electron to phonon dominated heat conduction in metal films bounded by dielectrics.
周期性多层复合材料中的热传导在周期小于相关自由程时可能会受到非平衡电子-声子散射的强烈影响。在这里,我们认为另外两个机制——垂直于金属膜的准弹道声子输运和非弹性电子-界面散射——也可以影响周期小于 10nm 的金属/电介质多层结构中的传导。测量使用了六不同桥宽的 3ω 方法,宽度低至 50nm,以提取 Mo/Si(2.8nm/4.1nm)多层膜的纵横有效电导率,分别为 15.4 和 1.2W/mK。横平面热阻低于考虑体积和界面散射所能预测的值,但与围绕金属中声子-电子能量转换的膜法向长度尺度建立的新模型一致。我们引入了一个在由电介质限定的金属膜中从电子主导传热到声子主导传热的转变判据。