Chemical & Materials Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA.
Angew Chem Int Ed Engl. 2012 Jun 25;51(26):6356-60. doi: 10.1002/anie.201201959. Epub 2012 May 8.
Shining light on Zeise: In a study of Zeise's anion, PtCl(3)(C(2)H(4)), and its bromine and iodine analogues, electronic structure information for each species, derived from spectral features, is assigned through calculations at the coupled cluster level of theory. The calculations indicate that the electron binding energies decrease with halogen size and that there is a synergistic η(2) interaction between C(2)H(4) and the PtX(3)(-) anions.
在对泽塞阴离子 PtCl(3)(C(2)H(4)) 及其溴和碘类似物的研究中，通过耦合团簇理论水平的计算，对各物种的光谱特征进行了电子结构信息的分配。计算表明，电子结合能随卤素原子尺寸的增大而降低，并且 C(2)H(4)与 PtX(3)(-)阴离子之间存在协同的 η(2)相互作用。
