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新型有机官能化多钒酸盐的可控溶剂热合成。

Controlled solvothermal synthesis of novel organic functionalized polyoxovanadates.

机构信息

Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, Beijing 100081, PR China.

出版信息

Dalton Trans. 2012 Jun 21;41(23):6910-3. doi: 10.1039/c2dt30660c. Epub 2012 May 11.

DOI:10.1039/c2dt30660c
PMID:22580947
Abstract

Four novel organic functionalized polyoxovanadates are solvothermally synthesized by altering the reaction temperature and using different organoarsonic acids. These POVs are fully characterized and the phase transitions between different POVs structures are confirmed by X-ray diffraction analyses. Such a transition is temperature-dependent and thus controlled synthesis of new POVs can be achieved.

摘要

四种新型有机功能化多钒酸盐通过改变反应温度和使用不同的有机胂酸来溶剂热合成。这些 POV 被充分表征，并且通过 X 射线衍射分析证实了不同 POV 结构之间的相变。这种转变是温度依赖的，因此可以实现新 POV 的控制合成。

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