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链状聚[[[三水合钴(II)]-μ-10-甲基吩噻嗪-3,7-二羧酸根合]一水合物]

catena-Poly[[[triaqua-cobalt(II)]-μ-10-methyl-phenothia-zine-3,7-dicarboxyl-ato] monohydrate].

作者信息

Hu Yun-Xia, Zhou Yan, Wang Fang-Ming, Zhang Wen-Wei

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m402-3. doi: 10.1107/S1600536812009580. Epub 2012 Mar 10.

Abstract

The polymeric title compound, {[Co(C(15)H(9)NO(4)S)(H(2)O)(3)]·H(2)O}(n), consists of chains along [001] made up from Co(2+) ions bridged by 10-methyl-phenothia-zine-3,7-dicarboxyl-ate anions. The Co(2+) ion, coordinated by three O atoms from two different carboxyl-ate groups and three water mol-ecules, displays a distorted octa-hedral environment. In the crystal, π-π inter-chain inter-actions, with centroid-centroid distances of 3.656 (2) and 3.669 (2) Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O-H⋯O hydrogen-bonding inter-actions between the coordinating water mol-ecules and carboxyl-ate O atoms link the sheets into a three-dimensional network.

摘要

聚合标题化合物{[Co(C₁₅H₉NO₄S)(H₂O)₃]·H₂O}ₙ由沿[001]方向的链组成,这些链由10 - 甲基 - 吩噻嗪 - 3,7 - 二羧酸根阴离子桥连的Co²⁺离子构成。Co²⁺离子由来自两个不同羧酸根基团的三个O原子和三个水分子配位,呈现出扭曲的八面体环境。在晶体中,配体苯环之间质心 - 质心距离为3.656(2)和3.669(2) Å的π - π链间相互作用将链组装成平行于(100)的片层。配位水分子与羧酸根O原子之间的O - H⋯O氢键相互作用将片层连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0cf8/3343812/4b69558731d3/e-68-0m402-fig1.jpg

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