水合氯{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-κ(2)O(1),N,N',O(1')}钴(III) 二甲基甲酰胺单溶剂合物
Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(2)O(1),N,N',O(1')}cobalt(III) dimethyl-formamide monosolvate.
作者信息
Wei Yun, Pang Ting, Liu Jiacheng, Li Meng, Liang Lili
机构信息
College of Chemistry and Chemical Engineering, Key Laboratory of Eco-Environment-Related Polymer Materials of the Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu, Northwest Normal University, Lanzhou 730070, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m455-6. doi: 10.1107/S1600536812011324. Epub 2012 Mar 21.
In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetra-dentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethyl-formamide (DMF) monosolvate. In the crystal, complex mol-ecules are linked via O-H(water)⋯O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C-H⋯Cl inter-action, and the DMF mol-ecule is linked to the complex mol-ecule by C-H⋯O inter-actions.
在标题化合物[Co(C₁₈H₁₈N₂O₄)Cl(H₂O)]·C₃H₇NO中，Co(III)离子由一个四齿的6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨甲基亚甲基)]二酚盐配体六配位，在顶端位置有一个氯离子和一个水配体。该化合物结晶为二甲基甲酰胺(DMF)单溶剂化物。在晶体中，配合物分子通过O-H(水)⋯O氢键相连形成类似二聚体的排列。这些二聚体通过C-H⋯Cl相互作用相连，DMF分子通过C-H⋯O相互作用与配合物分子相连。
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