• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一水合氯·{6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨基二甲基亚基)]二酚根合-κO,N,N',O}钴(III)

Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolato-κO,N,N',O}cobalt(III) monohydrate.

作者信息

Xing Jianxin

机构信息

Department of Biology, Dezhou University, Dezhou 253023, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 31;65(Pt 4):m468. doi: 10.1107/S1600536809011167.

DOI:10.1107/S1600536809011167
PMID:21582398
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968959/
Abstract

The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octa-hedral cobalt(III) complex with a 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent mol-ecule (half-occupancy). The Co(III) ion is coordinated in an N(2)O(3)Cl manner. Weak O-H⋯O hydrogen bonds may help to stabilize the crystal packing.

摘要

标题化合物[Co(C₁₈H₁₈N₂O₄)Cl(H₂O)]·H₂O包含一个扭曲的八面体钴(III)配合物，其具有一个6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(亚氨基二甲基亚基)]二酚盐配体、一个氯和一个水配体，还有一个无序的水溶剂分子（占据率为一半）。Co(III)离子以N₂O₃Cl的方式配位。弱的O—H⋯O氢键可能有助于稳定晶体堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ccba/2968959/3bed4cc1e52f/e-65-0m468-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ccba/2968959/3bed4cc1e52f/e-65-0m468-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ccba/2968959/3bed4cc1e52f/e-65-0m468-fig1.jpg

相似文献

1
Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolato-κO,N,N',O}cobalt(III) monohydrate.一水合氯·{6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨基二甲基亚基)]二酚根合-κO,N,N',O}钴(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 31;65(Pt 4):m468. doi: 10.1107/S1600536809011167.
2
Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(2)O(1),N,N',O(1')}cobalt(III) dimethyl-formamide monosolvate.水合氯{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-κ(2)O(1),N,N',O(1')}钴(III) 二甲基甲酰胺单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m455-6. doi: 10.1107/S1600536812011324. Epub 2012 Mar 21.
3
The cocrystal aqua-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}-manganese(III)-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(methanol-κO)manganese(III) (1/1).氯代水合{6,6'-二叔丁基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚根合-κO,N,N',O'}-锰(III)-氯代{6,6'-二叔丁基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚根合-κO,N,N',O'}(甲醇-κO)锰(III) (1/1)
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 4;64(Pt 5):m626-7. doi: 10.1107/S1600536808006818.
4
{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I).{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二亚基双(腈基亚甲基)]二苯酚根合 - 1κO,O,O,O:2κO,N,N',O}(甲醇 - 1κO)(高氯酸根 - 1κO)铜(II)钠(I)
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m445. doi: 10.1107/S1600536809010356.
5
Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.高氯酸二水合-{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III) 18-冠-6半溶剂合物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m153. doi: 10.1107/S1600536808044176.
6
Aqua-(dicyanamido){μ-6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II)sodium.水合 -（二氰胺基）{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二亚基双（腈基亚甲基）]二酚根合}镍（II）钠
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m557. doi: 10.1107/S160053680901438X.
7
Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.水合-{6,6-二甲氧基-2,2'-[丙烷-1,3-二基双(腈基亚甲基)]二酚根合-κO,N,N',O'}铜(II)乙腈溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):m1658. doi: 10.1107/S1600536809049137.
8
Aqua-cyanido{6,6'-dimeth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idene)]diphenolato}cobalt(III) acetonitrile hemisolvate.水合氰基{6,6'-二甲氧基-2,2'-[1,2-亚苯基双(次氮基甲烷亚基)]二酚根合}钴(III)乙腈半溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m61. doi: 10.1107/S160053681105330X. Epub 2011 Dec 17.
9
{6,6'-Dieth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}(2-eth-oxy-6-formyl-phenolato)cobalt(III)-ethanol-water (1/1/1).{6,6'-二乙氧基-2,2'-[2,2-二甲基丙烷-1,3-二亚基双(亚氨甲基亚炔基)]二酚根合}(2-乙氧基-6-甲酰基酚根合)钴(III)-乙醇-水(1/1/1)
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):m366-7. doi: 10.1107/S1600536810007622.
10
Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(formato-κO)manganese(III) dihydrate.水合-{6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨甲基亚基)]二酚根合-κO,N,N',O'}(甲酸根合-κO)锰(III)二水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m746. doi: 10.1107/S1600536811017648. Epub 2011 May 14.

引用本文的文献

1
Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(2)O(1),N,N',O(1')}cobalt(III) dimethyl-formamide monosolvate.水合氯{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-κ(2)O(1),N,N',O(1')}钴(III) 二甲基甲酰胺单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m455-6. doi: 10.1107/S1600536812011324. Epub 2012 Mar 21.

本文引用的文献

1
[μ-N,N'-Bis(3-meth-oxy-2-oxidobenzyl-idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate.[μ-N,N'-双(3-甲氧基-2-氧化苄叉基)丙烷-1,3-二胺]三硝酸铜(II)铽(III)丙酮溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m406. doi: 10.1107/S1600536808002080.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
A carboxylato-supported alkoxo-bridged dimanganese(III) complex: bis(mu-benzoato-O:O')bis[3-(33-methoxysalicydeneamino)propanolato-O,N,O':O']dimanganese(III).
Acta Crystallogr C. 2001 Jun;57(Pt 6):719-20. doi: 10.1107/s0108270101005790. Epub 2001 Jun 12.