一水合氯·{6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨基二甲基亚基)]二酚根合-κO,N,N',O}钴(III)
Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolato-κO,N,N',O}cobalt(III) monohydrate.
作者信息
Xing Jianxin
机构信息
Department of Biology, Dezhou University, Dezhou 253023, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 31;65(Pt 4):m468. doi: 10.1107/S1600536809011167.
The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octa-hedral cobalt(III) complex with a 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-dimethyl-idyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent mol-ecule (half-occupancy). The Co(III) ion is coordinated in an N(2)O(3)Cl manner. Weak O-H⋯O hydrogen bonds may help to stabilize the crystal packing.
标题化合物[Co(C₁₈H₁₈N₂O₄)Cl(H₂O)]·H₂O包含一个扭曲的八面体钴(III)配合物，其具有一个6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(亚氨基二甲基亚基)]二酚盐配体、一个氯和一个水配体，还有一个无序的水溶剂分子（占据率为一半）。Co(III)离子以N₂O₃Cl的方式配位。弱的O—H⋯O氢键可能有助于稳定晶体堆积。
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