Ha Kwang
School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m479. doi: 10.1107/S1600536812011907. Epub 2012 Mar 24.
The Pt(II) ion in the title complex, [PtI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl-amine (dpa) ligand and by two I(-) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 52.8 (3)°. Pairs of complex mol-ecules are assembled through inter-molecular N-H⋯I hydrogen bonds, forming a dimer-type species. The complexes are stacked in columns along the b axis and display several inter-molecular π-π inter-actions between the pyridine rings, with a shortest ring centroid-centroid distance of 3.997 (5) Å.
在标题配合物[PtI₂(C₁₀H₉N₃)]中，Pt(II)离子在由螯合二-2-吡啶胺（dpa）配体的两个吡啶N原子和两个I⁻阴离子所定义的扭曲平面四边形环境中呈四配位。dpa配体不是平面的，吡啶环之间的二面角为52.8 (3)°。配合物分子对通过分子间N-H⋯I氢键组装，形成二聚体型物种。这些配合物沿b轴堆积成列，并且在吡啶环之间表现出几种分子间π-π相互作用，最短的环心距为3.997 (5) Å。
