Fun Hoong-Kun, Chia Tze Shyang, Samshuddin S, Narayana B, Sarojini B K
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1560-1. doi: 10.1107/S160053681201820X. Epub 2012 Apr 28.
In the title compound, C(28)H(18)F(4)O(2), the central benzene ring makes dihedral angles of 44.27 (6), 56.33 (5) and 77.27 (6)° with the two adjacent fluoro-benzene rings and terminal difluoro-substituted benzene ring, respectively. The dihedral angle between the fluoro-benzene rings is 87.81 (6)°. The meth-oxy and prop-2-en-1-one groups are essentially coplanar with their attached benzene rings, as indicated by their C-O-C(ar)-C(ar) [-0.06 (15)°] and C-C-C(ar)-C(ar) [4.5 (2)°] (ar = aromatic) torsion angles. In the crystal, mol-ecules are linked by C-H⋯F and C-H⋯O hydrogen bonds into sheets lying parallel to the ac plane. The crystal structure also features C-H⋯π inter-actions.
在标题化合物C₂₈H₁₈F₄O₂中,中心苯环与两个相邻的氟苯环和末端二氟取代苯环分别形成44.27 (6)°、56.33 (5)°和77.27 (6)°的二面角。氟苯环之间的二面角为87.81 (6)°。甲氧基和2-丙烯-1-酮基团与其相连的苯环基本共面,其C-O-C(芳基)-C(芳基)[-0.06 (15)°]和C-C-C(芳基)-C(芳基)4.5 (2)°扭转角表明了这一点。在晶体中,分子通过C-H⋯F和C-H⋯O氢键连接成平行于ac平面的片层。晶体结构还具有C-H⋯π相互作用。