Ourari Ali, Baameur Lotfi, Bouet Gilles, Allain Magali
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1141. doi: 10.1107/S1600536812010550. Epub 2012 Mar 24.
In the title Schiff base, C(29)H(26)N(2)O(4), the complete molecule is generated by a crystallographic twofold axis and is V-shaped. The planes of the benzene rings of the central diphenyl-methane unit make a dihedral angle of 78.11 (4)° while adjacent benzene and 5-meth-oxy-salicyl-idene rings are twisted with respect to each other by a dihedral angle of 11.84 (8)°. The Schiff base is in the enol-imino form and an intra-molecular O-H⋯N hydrogen bond is observed.
在席夫碱C(29)H(26)N(2)O(4)的标题中,整个分子由一个晶体学二重轴生成,呈V形。中心二苯甲烷单元的苯环平面形成的二面角为78.11 (4)°,而相邻的苯环和5-甲氧基水杨醛环相对于彼此扭转的二面角为11.84 (8)°。席夫碱处于烯醇-亚胺形式,并且观察到分子内O-H⋯N氢键。