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利用新型杂化催化剂从木质纤维素生物质中优化生产乙酰丙酸。

Optimization of levulinic acid from lignocellulosic biomass using a new hybrid catalyst.

机构信息

Chemical Reaction Engineering Group (CREG), Energy Research Alliance, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM, Skudai, Johor, Malaysia.

出版信息

Bioresour Technol. 2012 Jul;116:58-65. doi: 10.1016/j.biortech.2012.03.097. Epub 2012 Apr 10.

Abstract

Conversion of glucose, empty fruit bunch (efb) and kenaf to levulinic acid over a new hybrid catalyst has been investigated in this study. The characterization and catalytic performance results revealed that the physico-chemical properties of the new hybrid catalyst comprised of chromium chloride and HY zeolite increased the levulinic acid production from glucose compared to the parent catalysts. Optimization of the glucose conversion process using two level full factorial designs (2(3)) with two center points reported 55.2% of levulinic acid yield at 145.2 °C, 146.7 min and 12.0% of reaction temperature, reaction time and catalyst loading, respectively. Subsequently, the potential of efb and kenaf for producing levulinic acid at the optimum conditions was established after 53.2% and 66.1% of efficiencies were reported. The observation suggests that the hybrid catalyst has a potential to be used in biomass conversion to levulinic acid.

摘要

本研究考察了在新型混合催化剂的作用下,葡萄糖、空果串(EFB)和麻疯树转化为戊酸的情况。表征和催化性能结果表明,与母体催化剂相比,由氯化铬和 HY 沸石组成的新型混合催化剂的物理化学性质提高了葡萄糖转化为戊酸的产量。使用具有两个中心点的 2(3)全因子设计(2(3))对葡萄糖转化过程进行优化,在 145.2°C、146.7 分钟和 12.0%的反应温度、反应时间和催化剂负载条件下,报告了 55.2%的戊酸收率。随后,在报告的效率分别为 53.2%和 66.1%的情况下,确定了 EFB 和麻疯树在最佳条件下生产戊酸的潜力。这一观察结果表明,该混合催化剂具有用于生物质转化为戊酸的潜力。

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