Wang Shu-Fang, Wang Li-Ya, Wang Xiao-Hong, Lin Pei, Liu Jiu-Rong, Xin Bao-Dong, He Guo-Ping
Beijing Institute of Hydrogeology and Engineering Geology, Beijing 100195, China.
Huan Jing Ke Xue. 2012 Mar;33(3):760-70.
Investigation and numerical simulation, based on RT3D (reactive transport in 3-dimensions)were used to identify the source of tetrachloroethylene (PCE) and trichloroethylene (TCE) in the groundwater of a city in the north of China and reverse the input intensity. Multiple regressions were applied to analyze the influenced factors of input intensity of PCE and TCE using Stepwise function in Matlab. The results indicate that the factories and industries are the source of the PCE and TCE in groundwater. Natural attenuation was identified and the natural attenuation rates are 93.15%, 61.70% and 61.00% for PCE, and 70.05%, 73.66% and 63.66% for TCE in 173 days. The 4 source points identified by the simulation have released 0.910 6 kg PCE and 95.693 8 kg TCE during the simulation period. The regression analysis results indicate that local precipitation and the thickness of vadose zone are the main factors influencing organic solution transporting from surface to groundwater. The PCE and TCE concentration are found to be 0 and 5 mg x kg(-1) from surface to 35 cm in vadose zone. All above results suggest that PCE and TCE in groundwater are from the source in the surface. Natural attenuation occurred when PCE and TCE transporting from the surface to groundwater, and the rest was transported to groundwater through vadose zone. Local precipitation was one of the critical factors influencing the transportation of PCE and TCE to aquifer through sand, pebble and gravel of the Quaternary.
基于三维反应输运(RT3D)模型进行调查和数值模拟,以确定中国北方某城市地下水中四氯乙烯(PCE)和三氯乙烯(TCE)的来源,并反推其输入强度。运用多元回归,利用Matlab中的逐步函数分析PCE和TCE输入强度的影响因素。结果表明,工厂和工业活动是地下水中PCE和TCE的来源。确定了自然衰减现象,在173天内,PCE的自然衰减率分别为93.15%、61.70%和61.00%,TCE的自然衰减率分别为70.05%、73.66%和63.66%。模拟确定的4个源点在模拟期内已释放0.910 6 kg的PCE和95.693 8 kg的TCE。回归分析结果表明,当地降水量和包气带厚度是影响有机溶液从地表向地下水运移的主要因素。在包气带从地表至35 cm深度范围内,PCE和TCE浓度分别为0和5 mg·kg⁻¹。以上所有结果表明,地下水中的PCE和TCE来自地表源。PCE和TCE从地表向地下水运移过程中发生了自然衰减,其余部分通过包气带运移至地下水。当地降水量是影响PCE和TCE通过第四纪的砂、卵石和砾石向含水层运移的关键因素之一。