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使用三官能有机烷氧基硅烷作为分散剂合成有机-无机杂化溶胶。

Synthesis of organic-inorganic hybrid sols using trifunctional organoalkoxysilanes for dispersion agents.

作者信息

Park Hoyyul, Kang Dongjun, Ahn Myeongsang, Lee Hyeonhwa

机构信息

Advanced Materials and Application Research Division, Korea Electrotechnology Research Institute, 641-120, Korea.

出版信息

J Nanosci Nanotechnol. 2012 Feb;12(2):1692-5. doi: 10.1166/jnn.2012.4666.

DOI:10.1166/jnn.2012.4666
PMID:22630031
Abstract

We investigated the properties of synthetically produced organic-inorganic hybrid coatings by a sol-gel process. The properties of organic-inorganic hybrid materials arise from the synergism between the properties of the individual components. One of the typical way to synthesize the organic-inorganic hybrid materials is to use silica and silanes. A colloidal silica sol was used as an inorganic material. Methyltrimethoxysilane and phenyltrimethoxysilane were used as the trifunctional organoalkoxysilanes. Hybrid sols of colloidal silica and silanes were synthesized as a function of reaction time and methyltrimethoxysilane/phenyltrimethoxysilane ratio by a sol-gel process. Physical properties of sol solutions such as stability, viscosity, and transmittance were investigated. The surface roughness and surface free energy of the coatings were also measured.

摘要

我们通过溶胶-凝胶法研究了合成制备的有机-无机杂化涂层的性能。有机-无机杂化材料的性能源于各组分性能之间的协同作用。合成有机-无机杂化材料的一种典型方法是使用二氧化硅和硅烷。胶体二氧化硅溶胶用作无机材料。甲基三甲氧基硅烷和苯基三甲氧基硅烷用作三官能有机烷氧基硅烷。通过溶胶-凝胶法,根据反应时间和甲基三甲氧基硅烷/苯基三甲氧基硅烷比例合成了胶体二氧化硅和硅烷的杂化溶胶。研究了溶胶溶液的物理性质,如稳定性、粘度和透光率。还测量了涂层的表面粗糙度和表面自由能。

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