Department of Chemistry, K. N. Toosi University of Technology, 1587-4416 Tehran, Iran.
Phys Chem Chem Phys. 2012 Jul 7;14(25):9214-8. doi: 10.1039/c2cp40920h. Epub 2012 May 30.
The superposition of chiral states of chiral molecules, as delocalized quantum states of a many-particle system, can be used for the experimental investigations of decoherence theory. In this regard, a great challenge is the precise quantification of the robustness of these superpositions against environmental effects. The methods so far proposed need the detailed specification of the internal states of the molecule, usually requiring heavy numerical calculations. Here, by using the linearized quantum Boltzmann equation and by borrowing ideas employed for analyzing other quantum systems, we present a general and simple approach, of wide applicability, which can be used to compute the dominant contribution to the decoherence rate for the superpositions of chiral states of chiral molecules, due to environmental scattering.
手性分子的手性态的叠加,作为多粒子系统的非定域量子态,可以用于退相干理论的实验研究。在这方面,一个巨大的挑战是精确量化这些叠加对环境影响的鲁棒性。到目前为止提出的方法需要对分子的内部状态进行详细说明,通常需要进行大量的数值计算。在这里,我们通过使用线性量子波尔兹曼方程,并借鉴用于分析其他量子系统的思想,提出了一种通用且简单的方法,该方法具有广泛的适用性,可以用于计算由于环境散射引起的手性分子手性态叠加的退相干率的主要贡献。