Department of Chemistry, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, Japan.
Angew Chem Int Ed Engl. 2012 Jul 16;51(29):7236-41. doi: 10.1002/anie.201202560. Epub 2012 May 29.
Cut into pieces: The π-electron distribution in nanographene fragments isolated between oxidized graphene areas is investigated using scanning probe microscopy (see picture). The edge-shape-dependent localization and migration of the Clar sextet explains the observed π-state distributions and enables investigation of the electronic properties.
使用扫描探针显微镜研究了氧化石墨烯区域之间隔离的纳米石墨烯碎片中的π电子分布(见图)。Clar 六重态的边缘形状依赖性定位和迁移解释了观察到的π态分布,并能够研究其电子性质。