National Institute of Clean-and-low-carbon Energy, Beijing, 102209, China.
Chem Soc Rev. 2012 Jul 21;41(14):4909-27. doi: 10.1039/c2cs35086f. Epub 2012 May 31.
Great progress has been made in the preparation and application of ordered mesoporous metal oxides during the past decade. However, the applications of these novel and interesting materials have not been reviewed comprehensively in the literature. In the current review we first describe different methods for the preparation of ordered mesoporous metal oxides; we then review their applications in energy conversion and storage, catalysis, sensing, adsorption and separation. The correlations between the textural properties of ordered mesoporous metal oxides and their specific performance are highlighted in different examples, including the rate of Li intercalation, sensing, and the magnetic properties. These results demonstrate that the mesoporosity has a direct impact on the properties and potential applications of such materials. Although the scope of the current review is limited to ordered mesoporous metal oxides, we believe that the information may be useful for those working in a number of fields.
在过去的十年中，有序介孔金属氧化物的制备和应用取得了巨大的进展。然而，这些新型有趣材料的应用尚未在文献中得到全面综述。在当前的综述中，我们首先描述了制备有序介孔金属氧化物的不同方法；然后综述了它们在能量转换和存储、催化、传感、吸附和分离中的应用。在不同的例子中强调了有序介孔金属氧化物的结构性质与其特定性能之间的相关性，包括锂离子的嵌入速率、传感和磁性。这些结果表明介孔性对这些材料的性质和潜在应用有直接的影响。尽管当前综述的范围仅限于有序介孔金属氧化物，但我们相信这些信息可能对许多领域的工作者有用。
