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β-环糊精-钴铁氧体纳米复合材料作为增强的儿茶酚检测传感平台。

β-cyclodextrin-cobalt ferrite nanocomposite as enhanced sensing platform for catechol determination.

机构信息

College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.

出版信息

Colloids Surf B Biointerfaces. 2012 Oct 1;98:58-62. doi: 10.1016/j.colsurfb.2012.05.003. Epub 2012 May 12.

Abstract

An electrochemical sensor based on β-cyclodextrin-cobalt ferrite nanocomposite was developed for the sensitive detection of catechol (CT). To construct the base of the sensor, a novel composite was initially fabricated and used as the substrate material by combining cobalt ferrite nanocomposite and β-cyclodextrin via a simple sonication-induced assembly. Due to the high catechol-loading capacity on the electrode surface and the upstanding electric conductivity of cobalt ferrite nanocomposite, the electrochemical response of the fabricated sensor was greatly enhanced and displayed excellent analytical performance for catechol detection from 1 to 200 μM with a low detection limit of 0.12 μM (S/N=3). Moreover, the developed electrochemical sensor exhibited good selectivity and acceptable reproducibility and could be used for the detection of catechol in water samples.

摘要

基于β-环糊精-钴铁氧体纳米复合材料的电化学传感器被开发用于灵敏检测儿茶酚(CT)。为了构建传感器的基础,首先通过简单的超声诱导组装将钴铁氧体纳米复合材料与β-环糊精结合,制备了一种新型复合材料作为基底材料。由于电极表面具有高儿茶酚负载能力和钴铁氧体纳米复合材料的出色导电性,因此制备的传感器的电化学响应得到了极大增强,并对 1 至 200 μM 范围内的儿茶酚检测显示出出色的分析性能,检测限低至 0.12 μM(S/N=3)。此外,开发的电化学传感器表现出良好的选择性和可接受的重现性,可用于水样中儿茶酚的检测。

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