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纳米级 La(OH)3:Sm3+ 荧光粉的结构和光学特性研究。

Structural and optical characterization of nanosized La(OH)3:Sm3+ phosphor.

机构信息

Laser and Spectroscopy Laboratory, Physics Department, Banaras Hindu University, Varanasi 221005, UP, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2012 Oct;96:148-53. doi: 10.1016/j.saa.2012.05.021. Epub 2012 May 14.

Abstract

In the present work, Sm(3+) doped La(OH)(3) nano-phosphor (~40 nm) has been synthesized using combustion synthesis method and detailed structural and spectroscopic characterizations are carried out. On excitation with 532 nm, several photoluminescence peaks extending over green to NIR regions have been observed and assigned to be due to 4f-4f transitions of Sm(3+) ions. A bright orange-red perception is observed in annealed sample, which is 10 times higher than as synthesized sample. Time resolved emission spectroscopy reveals pronounced effect of heating, which induce good crystalline in the host.

摘要

在本工作中,使用燃烧合成法合成了 Sm(3+)掺杂的 La(OH)(3)纳米荧光粉(~40nm),并对其进行了详细的结构和光谱表征。在 532nm 的激发下,观察到几个扩展到绿光到近红外区域的光致发光峰,并归因于 Sm(3+)离子的 4f-4f 跃迁。在退火样品中观察到明亮的橙红色感知,比合成样品高 10 倍。时间分辨发射光谱揭示了加热的显著影响,这在宿主中诱导了良好的结晶。

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