一种含联噻吩骨架的 N-杂环卡宾：合成与配位化学。
An N-heterocyclic carbene containing a bithiophene backbone: synthesis and coordination chemistry.
机构信息
Department of Chemistry, Western University, 1151 Richmond Street, London, Ontario N6A 5B7, Canada.
出版信息
Inorg Chem. 2012 Jun 18;51(12):6776-83. doi: 10.1021/ic300494g. Epub 2012 Jun 6.
PMID:22671580
Abstract
A new N-heterocyclic carbene (NHC) containing a fused bithiophene backbone has been synthesized along with its silver(I) and BPh(3) complexes. The donor strength of this unique NHC has been determined from the IR stretching frequencies of the isolated NHC-Rh(CO)(2)Cl complex. The photophysical properties of all of the novel compounds have been investigated and are presented.
摘要
一种新型的含并噻吩骨架的 N-杂环卡宾（NHC）及其银（I）和 BPh（3）配合物被合成。通过孤立的 NHC-Rh（CO）（2）Cl 配合物的 IR 伸缩频率确定了该独特 NHC 的供电子强度。所有新化合物的光物理性质都已被研究并呈现出来。
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