N-酰化：一种有效降低含五元内酰胺单元共轭聚合物最低未占轨道能级的方法。
N-acylation: an effective method for reducing the LUMO energy levels of conjugated polymers containing five-membered lactam units.
机构信息
Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.
出版信息
Chem Commun (Camb). 2012 Jul 14;48(55):6960-2. doi: 10.1039/c2cc32184j. Epub 2012 Jun 7.
PMID:22673943
Abstract
N-acylation was studied as a method for reducing the LUMO energy levels of benzodipyrrolidone-based polymers. The N-acylated polymers showed reduced LUMO levels and improved reversibility of reductive doping compared with N-alkylated polymers. This method may also apply in other conjugated polymers with lactam repeating units.
摘要
N-酰化被研究作为一种降低苯并二吡咯酮基聚合物的最低未占轨道能级的方法。与 N-烷基化聚合物相比，N-酰化聚合物显示出更低的 LUMO 水平和更高的还原掺杂可逆性。这种方法也可能适用于具有内酰胺重复单元的其他共轭聚合物。
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