• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

富勒烯有机金属配合物的配位模式和不同触感。

Coordination modes and different hapticities for fullerene organometallic complexes.

机构信息

Institute of Materials Research, National Autonomous University of Mexico, External Circuit, University City, Coyoacan 04510, Mexico City, Mexico.

出版信息

Molecules. 2012 Jun 12;17(6):7151-68. doi: 10.3390/molecules17067151.

DOI:10.3390/molecules17067151
PMID:22692240
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6268416/
Abstract

The different coordination modes in fullerene organometallic complexes are reviewed. The main modes are η2 and η5, but there are some interesting studies about the other four, all of them are revised in order to show which is the state of art of this kind of compounds with the respect of the hapticity.

摘要

富勒烯有机金属配合物中的不同配位模式进行了综述。主要模式为η2 和 η5,但也有一些关于其他四种模式的有趣研究,所有这些模式都进行了修订,以便展示在配体的触感方面,这类化合物的最新研究进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/9b02695cf9c6/molecules-17-07151-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/9e0483afbbec/molecules-17-07151-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/e3b84e22664a/molecules-17-07151-g002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/c8cbcc132fd0/molecules-17-07151-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/f63508486ddc/molecules-17-07151-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/8fb28f97144c/molecules-17-07151-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/54e56cc2c594/molecules-17-07151-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/2802ed43a202/molecules-17-07151-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/2a4eeb53bde3/molecules-17-07151-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/adb1033930af/molecules-17-07151-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/bc31f1c83193/molecules-17-07151-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/db9838ab3adf/molecules-17-07151-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/54c24ca947ef/molecules-17-07151-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/2294c95622c9/molecules-17-07151-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/a1f81f82bb21/molecules-17-07151-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/9b02695cf9c6/molecules-17-07151-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/9e0483afbbec/molecules-17-07151-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/e3b84e22664a/molecules-17-07151-g002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/c8cbcc132fd0/molecules-17-07151-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/f63508486ddc/molecules-17-07151-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/8fb28f97144c/molecules-17-07151-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/54e56cc2c594/molecules-17-07151-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/2802ed43a202/molecules-17-07151-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/2a4eeb53bde3/molecules-17-07151-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/adb1033930af/molecules-17-07151-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/bc31f1c83193/molecules-17-07151-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/db9838ab3adf/molecules-17-07151-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/54c24ca947ef/molecules-17-07151-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/2294c95622c9/molecules-17-07151-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/a1f81f82bb21/molecules-17-07151-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df97/6268416/9b02695cf9c6/molecules-17-07151-g015.jpg

相似文献

1
Coordination modes and different hapticities for fullerene organometallic complexes.富勒烯有机金属配合物的配位模式和不同触感。
Molecules. 2012 Jun 12;17(6):7151-68. doi: 10.3390/molecules17067151.
2
On the π coordination of organometallic fullerene complexes.关于有机金属富勒烯配合物的π配位。
Molecules. 2011 Jun 3;16(6):4652-9. doi: 10.3390/molecules16064652.
3
[Os3(CO)6(PMe3)3](mu3-eta2:eta2:eta2-C60)[Re3(mu-H)3(CO)9]: a fullerene[60] coordinated to two different trinuclear clusters.
Angew Chem Int Ed Engl. 2007;46(9):1436-9. doi: 10.1002/anie.200603882.
4
Metallosupramolecular receptors for fullerene binding and release.用于富勒烯结合和释放的金属超分子受体。
Chem Soc Rev. 2016 Jan 7;45(1):40-62. doi: 10.1039/c5cs00315f.
5
Photophysical and theoretical insights on fullerene/zincphthalocyanine supramolecular interaction in solution. fullerene/锌酞菁超分子相互作用在溶液中的光物理和理论见解。
J Phys Chem B. 2012 Oct 4;116(39):11979-98. doi: 10.1021/jp3052483. Epub 2012 Sep 20.
6
Coordinative interactions between porphyrins and C60, La@C82, and La2@C80.卟啉与 C60、La@C82 和 La2@C80 的协同相互作用。
Chemistry. 2013 Jan 7;19(2):558-65. doi: 10.1002/chem.201202661. Epub 2012 Nov 23.
7
Light-harvesting supramolecular porphyrin macrocycle accommodating a fullerene-tripodal ligand.容纳富勒烯三脚架配体的光捕获超分子卟啉大环
Chemistry. 2008;14(9):2827-41. doi: 10.1002/chem.200701720.
8
Supramolecular assemblies of tripodal porphyrin hosts and C60.三脚架状卟啉主体与C60的超分子组装体。
Chemistry. 2008;14(10):3035-44. doi: 10.1002/chem.200701686.
9
Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework.新型[60]富勒烯辅助的四铱蝴蝶骨架上的邻位膦化反应
Angew Chem Int Ed Engl. 2004 Mar 19;43(13):1712-4. doi: 10.1002/anie.200353290.
10
Supramolecular porphyrin-fullerene via 'two-point' binding strategy: axial-coordination and cation-crown ether complexation.通过“两点”结合策略构建的超分子卟啉-富勒烯:轴向配位和阳离子-冠醚络合
Chem Commun (Camb). 2005 Mar 14(10):1279-81. doi: 10.1039/b416736h. Epub 2005 Jan 19.

引用本文的文献

1
Capture of Fullerenes in Cages and Rings by Forming Metal-π Bond Arene Interactions.通过形成金属-π键芳烃相互作用在笼状和环状结构中捕获富勒烯
Materials (Basel). 2021 Jun 21;14(12):3424. doi: 10.3390/ma14123424.
2
Hydrocarbon-soluble, hexaanionic fulleride complexes of magnesium.镁的碳氢化合物可溶六阴离子富勒烯配合物。
Chem Sci. 2019 Oct 9;10(46):10755-10764. doi: 10.1039/c9sc03857d. eCollection 2019 Dec 14.
3
Organometallic complexes of carbon nanotori.碳纳米环的有机金属配合物。

本文引用的文献

1
Fullerenes encaging metal clusters--clusterfullerenes.富勒烯笼状金属簇——团簇富勒烯。
Chem Commun (Camb). 2011 Nov 21;47(43):11822-39. doi: 10.1039/c1cc12318a. Epub 2011 Jun 30.
2
On the π coordination of organometallic fullerene complexes.关于有机金属富勒烯配合物的π配位。
Molecules. 2011 Jun 3;16(6):4652-9. doi: 10.3390/molecules16064652.
3
Endohedral metallofullerenes: a unique host-guest association.金属包合物富勒烯:一种独特的主客体结合。
J Mol Model. 2019 Jul 23;25(8):239. doi: 10.1007/s00894-019-4118-0.
4
Exohedral complexes of large fullerenes, a theoretical approach.大型富勒烯的外表面配合物:一种理论方法
J Mol Model. 2017 May;23(5):171. doi: 10.1007/s00894-017-3346-4. Epub 2017 Apr 27.
Chem Soc Rev. 2011 Jul;40(7):3551-63. doi: 10.1039/c0cs00225a. Epub 2011 Apr 19.
4
Complexes of gold(I), silver(I), and copper(I) with pentaaryl[60]fullerides.金(I)、银(I)和铜(I)与五芳基[60]富勒烯的配合物。
J Am Chem Soc. 2011 May 4;133(17):6841-51. doi: 10.1021/ja201297r. Epub 2011 Apr 8.
5
The reactivity of endohedral fullerenes. What can be learnt from computational studies?笼型富勒烯的反应性。从计算研究中可以学到什么?
Phys Chem Chem Phys. 2011 Mar 7;13(9):3585-603. doi: 10.1039/c0cp01594f. Epub 2010 Nov 25.
6
Uniquely shaped double-decker buckyferrocenes--distinct electron donor-acceptor interactions.
J Am Chem Soc. 2008 Dec 3;130(48):16207-15. doi: 10.1021/ja8013902.
7
Crystal structure of osmylated c60: confirmation of the soccer ball framework.Osmiated C60 的晶体结构:对足球框架的确认。
Science. 1991 Apr 12;252(5003):312-3. doi: 10.1126/science.252.5003.312.
8
A theoretical study of fullerene-ferrocene hybrids.富勒烯 - 二茂铁杂化物的理论研究。
J Comput Chem. 2007 Jan 30;28(2):594-600. doi: 10.1002/jcc.20539.
9
Synthesis and electrochemistry of double-decker buckyferrocenes.双层巴基二茂铁的合成与电化学
J Am Chem Soc. 2006 Jun 7;128(22):7154-5. doi: 10.1021/ja061175x.
10
Peculiarities of C60*- coordination to cobalt(II) octaethylporphyrin in ionic multicomponent complexes: Observation of the reversible formation of Co-C(C60-) coordination bonds.离子多组分配合物中C60*与八乙基钴(II)卟啉配位的特性:Co-C(C60-)配位键可逆形成的观察
Chemistry. 2006 Jul 5;12(20):5225-30. doi: 10.1002/chem.200600132.