1,3-双(2,6-二异丙基苯基)-1H-咪唑-3-鎓氯化物二氯甲烷溶剂合物
1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium chloride dichloro-methane disolvate.
作者信息
Berger Matthias, Auner Norbert, Bolte Michael
机构信息
Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt am Main, Germany.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1844. doi: 10.1107/S1600536812022234. Epub 2012 May 23.
In the title compound, C(27)H(37)N(2) (+)·Cl(-)·2CH(2)Cl(2), the cation and the anion are each located on a crystallographic mirror plane. Both of the dichloro-methane solvent mol-ecules show a disorder across a mirror plane over two equally occupied positions. Additionally, one isopropyl group is also disordered. In the crystal, the cations are connected to the chloride ions via C-H⋯Cl hydrogen bonds.
在标题化合物C(27)H(37)N(2) (+)·Cl(-)·2CH(2)Cl(2)中，阳离子和阴离子均位于晶体学镜面平面上。两个二氯甲烷溶剂分子在镜面平面上跨越两个同等占据的位置呈现无序状态。此外，一个异丙基也无序。在晶体中，阳离子通过C—H⋯Cl氢键与氯离子相连。
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