Department of Environment Protection Engineering, University of Warmia and Mazury in Olsztyn, Olsztyn, Poland.
Environ Technol. 2012 Apr-May;33(7-9):821-7. doi: 10.1080/09593330.2011.597781.
The objective of this study was to determine the effect of an electric current on the effectiveness of reactive dye Reactive Black 5 (RB 5) adsorption onto two adsorbents: chitin and chitosan. The current density applied in the experiment was 50 A/m2. The experiment was carried out using electrodes made of stainless steel. At the first stage of the experiment - without the flow of electric current - the effectiveness of RB 5 dye adsorption onto chitin was determined at pH 3.0 and 5.0, whereas onto chitosan it was at pH 5.0. In the second stage, the effectiveness of RB 5 dye adsorption was determined onto chitin and chitosan with a simultaneous flow of direct current. In the case of both adsorbents, the pH value of the solution was 5.0. Results achieved in the study proved that the electric current had a positive effect on adsorption effectiveness onto chitin, as it contributed to an increase in the quantity of removed RB 5 dye to 440 mg/g d.m. from the initial 270 mg/g d.m. when assayed at the optimal pH 3.0 and from 135 mg/g d.m. when assayed at pH 5.0.
本研究的目的是确定电流对两种吸附剂(甲壳素和壳聚糖)上活性黑 5(RB 5)吸附效率的影响。实验中应用的电流密度为 50 A/m2。实验采用不锈钢电极进行。在实验的第一阶段——没有电流流动——在 pH 3.0 和 5.0 条件下确定 RB 5 染料在甲壳素上的吸附效率,而在 pH 5.0 条件下确定 RB 5 染料在壳聚糖上的吸附效率。在第二阶段,在直流同时流动的情况下,确定 RB 5 染料在甲壳素和壳聚糖上的吸附效率。对于两种吸附剂,溶液的 pH 值均为 5.0。研究结果表明,电流对吸附效率有积极影响,因为它有助于将初始条件下 pH 3.0 时吸附的 RB 5 染料从 270 mg/g d.m.增加到 440 mg/g d.m.,而在 pH 5.0 时从 135 mg/g d.m.增加到 440 mg/g d.m.。