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电流对壳聚糖和壳聚糖吸附效果的影响。

Effect of electric current on adsorption effectiveness on chitin and chitosan.

机构信息

Department of Environment Protection Engineering, University of Warmia and Mazury in Olsztyn, Olsztyn, Poland.

出版信息

Environ Technol. 2012 Apr-May;33(7-9):821-7. doi: 10.1080/09593330.2011.597781.

Abstract

The objective of this study was to determine the effect of an electric current on the effectiveness of reactive dye Reactive Black 5 (RB 5) adsorption onto two adsorbents: chitin and chitosan. The current density applied in the experiment was 50 A/m2. The experiment was carried out using electrodes made of stainless steel. At the first stage of the experiment - without the flow of electric current - the effectiveness of RB 5 dye adsorption onto chitin was determined at pH 3.0 and 5.0, whereas onto chitosan it was at pH 5.0. In the second stage, the effectiveness of RB 5 dye adsorption was determined onto chitin and chitosan with a simultaneous flow of direct current. In the case of both adsorbents, the pH value of the solution was 5.0. Results achieved in the study proved that the electric current had a positive effect on adsorption effectiveness onto chitin, as it contributed to an increase in the quantity of removed RB 5 dye to 440 mg/g d.m. from the initial 270 mg/g d.m. when assayed at the optimal pH 3.0 and from 135 mg/g d.m. when assayed at pH 5.0.

摘要

本研究的目的是确定电流对两种吸附剂(甲壳素和壳聚糖)上活性黑 5(RB 5)吸附效率的影响。实验中应用的电流密度为 50 A/m2。实验采用不锈钢电极进行。在实验的第一阶段——没有电流流动——在 pH 3.0 和 5.0 条件下确定 RB 5 染料在甲壳素上的吸附效率,而在 pH 5.0 条件下确定 RB 5 染料在壳聚糖上的吸附效率。在第二阶段,在直流同时流动的情况下,确定 RB 5 染料在甲壳素和壳聚糖上的吸附效率。对于两种吸附剂,溶液的 pH 值均为 5.0。研究结果表明,电流对吸附效率有积极影响,因为它有助于将初始条件下 pH 3.0 时吸附的 RB 5 染料从 270 mg/g d.m.增加到 440 mg/g d.m.,而在 pH 5.0 时从 135 mg/g d.m.增加到 440 mg/g d.m.。

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