Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, CAS Middle Tian Road, 18, Lanzhou, China.
Chem Commun (Camb). 2012 Aug 7;48(61):7586-8. doi: 10.1039/c2cc31438j. Epub 2012 Jun 26.
A Pd-Au/SiO(2) catalyst was prepared for the oxidative imination of toluenes with up to 99% yields in the absence of dehydrating agents under mild conditions. Nanoparticles with a PdO layer and PdO-Au core may be the active structure for the reaction.
一种 Pd-Au/SiO(2) 催化剂被制备用于在温和条件下，无需脱水剂的情况下，以高达 99%的收率氧化甲苯进行亚胺化反应。具有 PdO 层和 PdO-Au 核的纳米粒子可能是反应的活性结构。
