State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Inorg Chem. 2012 Jul 16;51(14):7587-91. doi: 10.1021/ic3003299. Epub 2012 Jun 27.
Two metal-organic frameworks constructed from nanosized Cu(20) and Cu(30) wheels have been obtained under hydrothermal conditions based on 1,2,3-triazole and 1-H-1,2,3-benzotriazole, respectively. Crystal structure analysis shows that their differences in the size and nuclearity of Cu(20) and Cu(30) wheels are attributed to the steric effect of ligands.
两种基于 1,2,3-三唑和 1-H-1,2,3-苯并三唑的纳米尺寸 Cu(20)和 Cu(30)轮的金属有机骨架在水热条件下得到。晶体结构分析表明，它们的 Cu(20)和 Cu(30)轮的尺寸和核数的差异归因于配体的空间位阻效应。
