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用于水净化的氧化铈纳米粒子吸附磷酸盐的初步研究;纳米粒子的合成与表征。

Preliminary study of phosphate adsorption onto cerium oxide nanoparticles for use in water purification; nanoparticles synthesis and characterization.

机构信息

Department of Chemical Engineering, Universitat Autònoma de Barcelona, Bellaterra, Spain.

出版信息

Water Sci Technol. 2012;66(3):503-9. doi: 10.2166/wst.2012.185.

Abstract

In this study, the synthesis and characterization of cerium oxide nanoparticles (CeO(2)-NPs) and their adsorption potential for removing phosphate from water was evaluated using a multi-factor experimental design to explore the effect of various factors on adsorption. The objective function selected was the percentage of phosphate removed from water, in which the phosphate concentration and the CeO(2)-NP concentration are quantitative variables (factors in the experimental design). A lineal polynomial fitted the experimental results well (R(2) = 0.9803). The nanostructure was studied by transmission electron microscopy (TEM) and high-resolution TEM techniques before and after the adsorption process. During the adsorption and desorption processes several changes in the morphology and surface chemistry of the CeO(2)-NPs were observed.

摘要

在这项研究中,使用多因素实验设计合成和表征了氧化铈纳米粒子(CeO(2)-NPs),并评估了其从水中去除磷酸盐的吸附潜力,以探索各种因素对吸附的影响。选择的目标函数是从水中去除的磷酸盐百分比,其中磷酸盐浓度和 CeO(2)-NP 浓度是定量变量(实验设计中的因素)。线性多项式很好地拟合了实验结果(R(2) = 0.9803)。在吸附和脱附过程前后,通过透射电子显微镜(TEM)和高分辨率 TEM 技术研究了纳米结构。在吸附和脱附过程中,观察到 CeO(2)-NPs 的形貌和表面化学性质发生了几次变化。

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