Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580, Japan.
Chem Commun (Camb). 2012 Aug 11;48(62):7750-2. doi: 10.1039/c2cc32706f. Epub 2012 Jun 29.
The Ru(II)-Pheox complex is an efficient catalyst for the intermolecular cyclopropanation of various terminal olefins with succinimidyl diazoacetate. This catalytic system can perform under mild conditions, and the desired cyclopropane products are obtained in high yields with excellent diastereoselectivity and enantioselectivity.
Ru(II)-Pheox 配合物是一种高效的催化剂,可用于各种末端烯烃与琥珀酰亚胺基重氮乙酸酯的分子间环丙烷化反应。该催化体系可以在温和条件下进行,所需的环丙烷产物以高收率、优异的非对映选择性和对映选择性得到。